If you have the names of volumes of partition the same, you cannot easily access both from Ambient.
For example:
SSD partition dh0:, volume System:
HDD partition dh0x:, volume System:
from Ambient you access only one System: - probably that one you boot from.
Theoretically can be possible to mount second System under other volumename using mountlist. I not tested it.
In case if you have also the same device names:
SSD partition dh0:, volume System:
HDD partition dh0:, volume System:
I suppose you cannot see second disk.
The same names could cause the case. The best way is to rename both devices and volumes on old disk to something like dh0x: Systemx: ... to have easy access to your old files from Ambient.
AmigaOS3: Amiga 1200
AmigaOS4: Micro A1-C, AmigaOne XE, Pegasos II, Sam440ep, Sam440ep-flex, Sam460LE, AmigaOneX1000
MorphOS: Efika 5200b, Pegasos I, Sam460LE, Pegasos II, Powerbook G4, Mac Mini, iMac G5, Powermac G5 Quad